The placings are unchanged at the top of the Primera Division with Barcelona still at the summit following victory over Xerez and just one point ahead of Real Madrid who edged past Real Zaragoza.
Barcelona suffered at times but eventually overcame rock-bottom Xerez, who ended the game with nine men.
Pep Guardiola's makeshift side suffered some nervy moments at 2-1 before Zlatan Ibrahimovic scored the all-important third goal after 55 minutes.
Barca had looked comfortable following early goals from Jeffren Suarez and Thierry Henry, but Mario Bermejo pulled one back immediately and Xerez missed a couple of great chances to level before Ibrahimovic's strike.
Matias Alustiza and Fabian Orellana were sent off for cynical tackles late on as Xerez's evening ended miserably.
Kaka made a fairytale return to action as he climbed off the bench to net a late winner for Real.
The £56million summer signing from AC Milan had missed the last six weeks with a groin problem but he was back with a bang tonight, netting the decider against 10-man Zaragoza soon after appearing as a 75th-minute substitute.
Earlier, Madrid had taken a 50th-minute lead through Raul but relegation-battling Zaragoza, despite having Matteo Contini sent off two minutes later, still managed to draw level through Adrian Colunga on the hour-mark.
Valencia edged a step closer to a place in next season's Champions League after easing past freefalling Deportivo La Coruna, whose own hopes of returning to Europe now look all but over.
David Villa's first-half penalty earned third-placed Valencia the spoils and Los Che provisionally move seven points clear of fourth-placed Real Mallorca, who play Malaga tomorrow.
Valencia finished the game with 10 men after substitute Ruben Baraja was sent off in injury-time, but it happened too late for ninth-placed Depor to take advantage as the Galician side's miserable run continued.
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